Monday, April 2, 2012

Chapter 8: Cyanide and the Death on the Nile

Is it any wonder why people are so afraid of everything these days? It is almost as if even thinking about taking a step outside can kill you. The scarier part is, staying indoors is just as dangerous. It seems as if nothing is safe: not the house you live in, not the food you prepare yourself, nor the air you breathe, and certainly not even the one you love. Cheryl Lewis made a fatal mistake: meeting John Allan. Of course, how was she supposed to know John was only into her for her money? Poor, naïve Cheryl. It seems like men these days just can’t be trusted. But that is not the only thing that comes with false advertising. Tylenol, the simplest of pain-relievers, and the most trusted by almost everyone, must now be inspected before even opening the package. Someone had the bright idea of contaminating it with a deadly poison, killing innocent patronages of local stores. But what does Cheryl Lewis and Tylenol has in common, you ask? The answer is rather simple: cyanide.
            John Allan and Cheryl Lewis met in 1993, both single, divorcees of previous marriages gone awry. Cheryl was a successful solicitor, and John, at this point, was a bum. He depended on social security and Cheryl’s income to survive. His degree in industrial chemistry from Hatfield Polytechnic, now the University of Hertfordshire, seems to have been a waste except for his access to cyanide and to upkeep his interesting hobby of collecting butterflies and preserving them. Next thing you know, he’ll be skinning his victims and making clothes out of them! Cheryl avoided such agony, thank goodness. In fact, Cheryl lucked out with just a nice evening drink. Gin and tonic, on the…cyanide! Vacationing near Luxor, Egypt, the two stayed in the New Winter Palace Hotel. Cheryl and John enjoyed a lovely dinner together, and soon after, Cheryl decided to shower. While she was indisposed, John spiked her gin and tonic with cyanide. Almost as soon as the drink hit her lips, the effects of the poison took action. The pain Cheryl was suffering was unbearable, and within minutes, she was sweating as if it was 110 degrees outside and her pulse was almost undetectable. Her skin was tinted blue, and she was foaming at the mouth while a curious odor was streaming from it, filling the room. Death followed shortly, and Cheryl’s death certificate read as heart failure and acute coronary thrombosis. After her body was brought home, and an autopsy was done. The pathologist found no trace of disease in Cheryl’s body that would cause such sudden death, but he did find an inflamed stomach. However, there was no analogous inflammation in her mouth or gullet, which would suggest that she consumed a drink laced with cyanide. Unfortunately, cyanide disappears from the tissue after death, and the fact that she had been embalmed before she was flown back home did not help the case either. The amount of smoking that Cheryl did also was an indicator that there would be more than a usual amount of cyanide in the body. There really was no other evidence to prove that she had been poisoned, except the shady findings of the investigation of John Allan.
            About a decade before the death of Cheryl Lewis took place, an unimaginable event took place in the United States. People were dropping like flies, right after they consumed Extra Strength Tylenol. The manufacturers really added extra strength, didn’t they?! People were being labeled as have suffering a massive stroke or heart attack. Coincidentally, these victims had all consumed the drug shortly before his or her death, but it was not coincidental in the fact that an unknown person had bought several bottles of Extra Strength Tylenol, replaced the contents with about sixty milligrams of potassium cyanide, and put them back on the shelf. After a suggestion that these symptoms that the victims suffered may have been from cyanide poisoning, and don’t you know, he was right. The contents of the Tylenol bottles that the victims used before their deaths had all contained between and ten poisoned pills. The pharmaceutical company recalled 31 million bottles, thinking that it was their blunder, when in fact, it was a random occurrence of purposeful poisoning.  
            Cyanide is actually the quickest acting of all the poisons. Allan could have been more considerate in choosing his poison for Cheryl though, at least let her enjoy her time in Luxor if she’s going to die anyway, amiright? At least she and those who thought Tylenol was safe did not suffer a long time. This highly poisonous chemical begins as a carbon atom and a nitrogen atom bonded together by a triple bond, compromising three electron pairs (Emsley, 2008, p.156). It is a highly reactive group and can form stable organic compounds, called nitriles (Emsley, 2008, p.156). Out of the different forms of cyanide that can be formed, hydrogen cyanide (HCN), is the deadliest as just a small amount inhaled can kill (Emsley, 2008, p.156). It is, in fact, a weak acid when dissolved in water, which is where its original name, prussic acid, was derived (Emsley, 2008, p.156). Cyanides are natural chemicals since the body does indeed need a slight trace of them to function because cyanide is a component of vitamin B12 as well as a component of [NiFe]-hydrogenase enzyme which catalyzes the oxidation of hydrogen (Emsley, 2008, p.157). A cobalt atom is at the center of the B12 atom to which the cyanide bonds for it forms a strong bond with metals because of its negative charge and its ability to form pi-bonds (Emsley, 2008, p.157). All of these are an important part of the B12 vitamin to which the body needs because without, the body will suffer from anemia, and synthesis of nucleic acids in DNA and of the amino acids in proteins will falter, creating more serious problems (Emsley, 2008, p.157).
            Cyanides are actually found in unexpected places, as they are used to manufacture a variety of products, such as cosmetics, nylon, Plexiglas, animal/poultry feed and a number of pharmacuticals including Celexa, Tagamet and Isoptin (Emsley, 2008, p.158). The only way that these products can include a form of a cyanide in their makeup is due to the fact that when bonded with a carbon atom in a larger molecule, cyanide loses its toxicity (Emsley, 2008, p.158). Another fun fact here is that cyanides are also found in very common foods, produced by plants, such as almonds and spinach, and seeds in the fruits of apples, cherries, apricots and peaches (Emsley, 2008, p.158). Because early ancient diets included mostly foods made up mostly by glycosides (cyanide-containing group in its molecular structure), the body evolved to fit  rhodanese, an enzyme  that  instantly detoxifies the cyanide radical by changing it to a thiocyanate group (-SCN) which is significantly less toxic (Emsley, 2008, p.159) The rhodanese enzyme is part of every human mitochondria so that adults can detoxify up to 1 gram of cyanide over a twenty-four hour period (Emsley, 2008, p.159).
            But what happens if the amount of cyanide consumed is greater than the rate at which the body can detoxify it? Serious problems occur, obviously. Hydrogen cyanide, if taken orally, will be absorbed across the gastrointestinal mucosa, which will then stimulate hyperventilation from an immediate response from the central nervous system (Hung et al., 2009). It can also lead to unconsciousness, if the dose is strong enough (Hung et al., 2009). Findings from a case report in which victims consume apricot seeds showed that victims suffered headache, vomiting, irritability, abdominal pain, dyspnoea, flushing, hypotension, hyptertension, hypoventilation, bright venous blood, and the smell of almonds on one’s breath (Akyildiz et al., 2009). The most severe side effect of cyanide poisoning is to go into a coma, if not death (Akylidiz et al., 2009). After ingestion of cyanide, the chemical is absorbed and circulated throughout the body, while it causes anoxia of the tissues by blocking cytochrome oxidase which can be seen in the heart, kidney and lungs (Akylidiz et al., 2009). Then anerobic metabolism occurs due to hypoxia, producing lactic acid (Akyildiz et al., 2009). What does all this mean, you ask? Simply, when the enzyme, cytochrome oxidase, can no longer function due to the blockage of cyanide, it becomes inactive, so the last transfer of electrons from that enzyme to the oxygen is blocked, and the chemical reactions that contribute the energy for imperative processes cannot progress which means you will die; cyanide is an irreversible enzyme inhibitor (Emsley, 2008, p.161). This means that the oxygen transported from the lungs can’t be utilized, which gives understanding as to why the blood turns a brighter color (Emsley, 2008, p.161). This color was probably the same color John Allan’s face turned when he was charged for the murder of Cheryl Lewis.
            On February 5, 1999, John Allan was arrested after an investigation of Cheryl’s death. Police found that Cheryl’s will was forged by John himself, as well as claims of thievery concerning Cheryl’s jewelry. In March of 2000, he was convicted and sentenced to life imprisonment. As for the Tylenol mystery, the crime was never solved, though there were those who followed in the footsteps, and tried to repeat the incident, but were caught sometime after. The original scoundrel was never found. Here lies yet another unsolved mystery. For every mystery, there is somewhere, somewhere, who knows the truth. Perhaps that someone is watching. Perhaps... it's you. Next time on Molecules of Murder...


Sources
Akyildiz, B. N., Kurtoğlu, S. S., Kondolot, M. M., & Tunç, A. A. (2010). Cyanide poisoning caused by ingestion of apricot seeds. Annals Of Tropical Paediatrics, 30(1), 39-43.  

Emsley, J. (2008). Molecules of murder: Criminal molecules and classic cases. The Royal Society of Publishing: U.K.

Hung, D., Tsan, Y., Yu, Y., & Hsu, C. (2009). Cyanide poisoning in taiwan. The Lancet, 374(9696), 1212-1212. 

Ending quote courtesy of Robert Stack:
http://mayclaire.res-alian.com/memoriam/rstack/movquotes.html

Image Courtesy of:
http://www.realmagick.com/hydrogen-cyanide/

 

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